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Mail merge in Word/Outlook 2010 using multiple email accounts in Outlook

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I use Outlook for my email client, for several external email addresses along with my ISP address in Verizon.  When doing a mail merge, I want to use one of the "other" email accounts, NOT the Verizon one (which is the first/main).  Unfortunately there is no option to choose which account the emails go out under unless I missed it.  I ran the mail merge and it went off successfully but the account the emails went out under was the ISP account with Verizon.  Since these emails are pertaining to a company to which I have an internal email address, I wanted the emails to go out under that account instead.  I have that account as one of the accounts in Outlook.  I also had it set to "Default" but still the emails went out under the main email account.

Please help.


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